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125 Phase I Selections from the 04.3 Solicitation

(In Topic Number Order)
JONAS, INC.
1113 Faun Road
Wilmington, DE 19803
Phone:
PI:
Topic#:
(302) 478-1375
Dr. Otakar Jonas
OSD 04-C01      Awarded: 15FEB05
Title:Smart Water Piping Corrosion and Scale Monitor
Abstract:This proposal covers the development and prototype testing of a new Smart Water Piping Corrosion and Scale Monitor for use in the main types of water based utility systems including: potable, closed and open cooling water, condensate, feedwater, and, after the project completion, electric cable cooling. The Monitor will have three main components: a new multi-parameter Corrosion and Scale Sensor, WaterExpert expert system (completion in Phase II), and control of chemical addition equipment by the expert system. The anticipated characteristics of the monitor are: multiple sensor surface probe; in-line, real time, direct detection of corrosion, scale, and MIC, comparison of monitored data to known corrosion rates and potential-pH data (diagrams), direct corrosion rate measurement with sensitivity less than 0.01 mm/year, feedback to chemical addition equipment, covers a variety of water systems, water chemistries, and materials, recommends optimum water treatment, rugged design, easy to replace (optional - replacement during operation), learning from experience (smart), automatic reporting and data storage for up to ten years, and as an option, can be installed on a short bypass loop outside of the pipe.

LUNA INNOVATIONS, INC.
2851 Commerce Street
Blacksburg, VA 24060
Phone:
PI:
Topic#:
(540) 552-5128
Tom Wavering
OSD 04-C01      Awarded: 08FEB05
Title:Fiber optic water corrosivity monitoring system
Abstract:Water piping systems maintenance is challenging due to cost and difficulty of maintaining optimal water chemistry. Advanced corrosion control systems are needed to actively monitor water corrosivity as feedback for the injection of green chemicals to maintain optimal water chemistry. Advanced corrosion control for water piping systems will result in reduced manpower costs and increased component life cycles. The Department of Defense estimates that a 1% improvement in Army utility O&M performance can save $18 million per year. To address this critical military need, Luna Innovations proposes to develop an optical fiber-based real-time water corrosivity monitoring system. The Phase I program will focus on the development and demonstration of the proposed sensor technology. The focus of the Phase II program will be to optimize sensor performance and validate performance through field testing. Luna has assembled the highly qualified, multidisciplinary team required for a successful program and has a history of bringing novel research from the laboratory to commercial markets.

PHYSICAL SCIENCES, INC.
20 New England Business Center
Andover, MA 01810
Phone:
PI:
Topic#:
(978) 689-0003
Mr. Edward J. Salley
OSD 04-C02      Awarded: 21JAN05
Title:A Water Sealant with Anti-microbial Functionality Developed for Concrete Surfaces and Deposited by Electrophoresis (7265-060)
Abstract:Physical Sciences Inc. proposes to electrophoretically deposit a coating of lithium silicate and photoactive titanium dioxide nanoparticles onto concrete providing a totally inorganic, room-temperature cured, concrete sealant. This coating scheme will be shown to not only reduce water permeability but will also benefit from the antimicrobial properties of the reactive titanium dioxide nanoparticles. The photoactive nature of the titanium dioxide will inhibit bacteria, mold, fungus, and algae growth on the concrete surface providing added long-term benefit. Phase 1 will validate the advantages of the proposed method via reduction in water permeability and demonstration of the anti-microbial functionality of the coating.

SPACE HARDWARE OPTIMIZATION TECHNOLOGY, INC.
7200 Highway 150
Greenville, IN 47124
Phone:
PI:
Topic#:
(812) 923-9591
Dr. Paul Todd
OSD 04-C02      Awarded: 02FEB05
Title:Investigation of Electrophoresis as a Novel Coating Mechanism for Sealing Concrete
Abstract:The U.S. Government is a heavy user of concrete structures for below-grade facilities, waterway, and marine applications. High hydraulic permeability of the concrete in these structures produces water intrusion into protected areas and accelerated corrosion of structures beyond their useful limits, necessitating costly maintenance, repairs and replacement. In response to this overwhelming problem, SHOT proposes to develop a novel coating system that uses electrophoresis for sealing concrete. Our research suggests that through an electrophoretic process, nanometer scale particles can be migrated into hardened cement paste, resulting in dramatically lower hydraulic permeability. Our previous experience in developing electrophoretic hardware provides an ideal foundation for the development of new hardware for application of this unique process. Our team will design and develop an ideal sealant/coating solution, as well as the equipment required to test coated concrete samples for their hydraulic permeability. The results of this testing and analysis will guide SHOT in designing equipment and optimizing the treatment coating solutions. The end product expected is a viable and effective concrete coating system we have called the SHOTr Electrophoretic Sealing System, which we plan to market under the trade name E-Seal.

FARADAY TECHNOLOGY, INC.
315 Huls Drive
Clayton, OH 45315
Phone:
PI:
Topic#:
(937) 836-7749
Dr. Maria Inman
OSD 04-C03      Awarded: 22FEB05
Title:High Frequency Pulse Reverse Electrochemical Treatment of Concrete for Mitigation of Corrosion
Abstract:This Phase I SBIR program addresses the critical need for effective dechlorination methods for corrosion protection of bridge deck and piers at US Army facilities. This program proposes an innovative electrochemical technology for dechlorination of concrete, which is cost-effective and suitable for large scale field applications, and adaptable to complex geometries while protecting the rebar within the concrete from further corrosion. The Phase I program will show that the proposed technology will remove chloride contaminants from concrete under an applied high frequency pulse reverse electric field, and accelerate the mass transport rate of ions, lowering operating costs and treatment times. To protect the rebar from corrosion during and after this process, corrosion inhibitors will be driven into the concrete structure using the applied electric field, and the rebar will also be protected using a pulsed cathodic protection system. The project team consists of Faraday Technology, Inc., an electrochemical engineering company that develops high frequency pulse reverse processes, and Terran Corporation, an environmental engineering firm specializing in the field installation and monitoring of direct current (DC) electroosmotic and electrokinetic remediation processes. The Phase I results would be transitioned into field trials in a Phase II program.

LUNA INNOVATIONS, INC.
2851 Commerce Street
Blacksburg, VA 24060
Phone:
PI:
Topic#:
(540) 552-5128
Dr. Bryan Koene
OSD 04-C04      Awarded: 10FEB05
Title:Intelligent Coatings for Self-Healing and Corrosion Control
Abstract:The bulk of current military coatings are expensive, contain volatile organics, and are labor intensive to apply. Much of these costs are associated with the scraping and repainting of metal materials (20% of the $10 billion in estimated Army corrosion-related costs). There is a tremendous need to develop intelligent coatings that can perform numerous functions above those historically demanded of coatings. Luna is addressing this need to enhance the service life of steel structures by developing an intelligent coating that will respond to a damage event to the coating and release (1) film-formers to heal the wound, (2) corrosion inhibitors to provide additional corrosion prevention to the site, and (3) passive indicators to mark the coating damage zone to alert maintenance personnel. In this Phase I SBIR, Luna will combine our recent successes in corrosion prevention, water-borne resin development, and specialty coating formulations chemistry using microcapsules to design a unique coating system that has the potential to meet multiple damage challenges to the same location.

NOMADICS, INC.
1024 S. Innovation Way
Stillwater, OK 74074
Phone:
PI:
Topic#:
(405) 372-9535
Dr. Sarah Westcott
OSD 04-C04      Awarded: 22FEB05
Title:Silica-Based Corrosion Protection Microcapsules
Abstract:Painting metal provides excellent corrosion protection, as long as the paint remains intact. However, if the paint peels or becomes chipped after an impact, corrosion can occur in the revealed metallic area and even spread underneath the paint. Therefore, regular inspection and maintenance are required to ensure that the paint remains undamaged. Repairs may be required for damage that occurs between inspections. As an alternative microcapsules incorporated in the paint can be used to store film-forming and corrosion preventative agents. When the paint is damaged, these agents are released and reform the paint before corrosion occurs. While microcapsules to incorporate water-insoluble pigments, organic monomers and organic corrosion inhibitors have been demonstrated, there has been little work with ionic, water-soluble corrosion inhibitors. Nomadics will apply our extensive experience in advanced materials to use silica-based microcapsules that contain water-soluble materials to supplement polymeric-capsules containing organic materials. These additives will help to achieve self-healing coatings that will have numerous applications in military and private sector applications.

CEMENT CHEMISTRY SYSTEMS, LP
1445 EAVES SPRING ROAD
MALVERN, PA 19355
Phone:
PI:
Topic#:
(800) 871-5291
Mr. BRUCE GRANT
OSD 04-C05      Awarded: 24FEB05
Title:Concrete Admixtures that Defend against Salt Scaling and Freeze-Thaw
Abstract:In cold climates, concretes are susceptible to deterioration from the combination of the use of deicing salts and cyclic freezing and thawing cycles. The presence of salts is reported to exacerbate the susceptibility of concrete to freeze-thaw deterioration. IPANEX is an admixture that has been in use for nearly 30 years and has a long track record of compatibility with plasticizers and air entraining admixtures. The mechanism by which IPANEX functions, however, has only recently been established. With the development of the understanding of how it works has come greater insight into applications beyond the initial scope of its usage. IPANEX is composed of 5 to 20 nanometer-sized particles of C-S-H [hydrous calcium silicate] that in application, seed the growth of C-S-H from the hydration of tri-calcium silicate. Seeding with nanometer-sized seeds means that a small dose rate will result in a large number of seeds distributed throughout the mass concrete. These seeds have the effect of removing the supersaturation that occurs with tri-calcium silicate and providing a more homogeneous microstructure. As part of this refined microstructure, there are no large growths of calcium hydroxide crystals; not even at the aggregate low density zones. The controlled growth does not necessarily result in less pores but rather in a pore structure that is generally finer. IPANEX will impact any process that relies upon the movement of fluids [water or gases] through the pore system of a concrete. As water freezes, it draws additional fluids from the gel pores, if the critical concentration of water in capillary pores is less than 91.7%, or if water can not be drawn from the gel pores, freeze-thaw deterioration will not be a problem. Furthermore, because of the pore sizes, water will not freeze in capillary pores. One school of thought on freeze-thaw deterioration suggests that osmotic pressures which develop between the freezing water in large pores and the capillary porosity result in different alkali concentrations and hence different pressure is a more or less significant contribution to this mode of deterioration. It is however considered as a major factor in salt scaling. The objective of this SBIR will be to demonstrate that IPANEX is compatible with air-entraining admixtures and will improve the durability of the concrete to salt scaling through the improvement in the microstructural development of the concrete.

BLUE ROAD RESEARCH
Clear Creek Business Park, 376 NE 219th Ave
Gresham, OR 97030
Phone:
PI:
Topic#:
(503) 667-7772
Mr. Eric Udd
OSD 04-C14      Awarded: 13DEC04
Title:Low Cost Corrosion/Corrosivity Sensor Systems For Ground Vehicles
Abstract:This proposal develops an extremely low cost fiber grating corrosion sensor system that could be deployed on a vehicle. Costs are estimated to be approximately $0.25 per sensor in volume allowing hundreds to be deployed if necessary on difficult to access areas of a ground vehicle. In order to keep costs to an absolute minimum it is anitipated that the read out unit would be maintenance rather then vehicle based. The system has the ability to be deployed and operated over a very wide range of temperatures and offers inherent temperature compensation. Because it is passive and dielectrically based it has very long potential life, limited mainly by corrosion of the material it is measuring.

DACCO SCI, INC.
10260 Old Columbia Road
Columbia, MD 21046
Phone:
PI:
Topic#:
(410) 381-9475
Dr. Guy D. Davis
OSD 04-C14      Awarded: 13DEC04
Title:Low-Cost EIS Corrosion Sensor for Ground Vehicles
Abstract:Corrosion of Army ground vehicles is a significant problem in cost, reliability, readiness, and safety. In many cases, the design of the vehicle relies solely or extensively on the protectiveness of the paint system for corrosion protection. DACCO SCI and Advanced Fluidics propose to develop a low-cost corrosion sensor system (sensor + electronics) that can directly monitor the coating health at the motor-pool level. In particular, this sensor system will provide early warning that the coating performance is degrading in contrast to corrosivity sensors that merely measure the corrosivity of the environment. The sensor is based on electrochemical impedance spectroscopy (EIS), which has proven successful in the laboratory for predicting coating performance. The sensors allow EIS to be performed in the field as a health monitoring method. The electronics module will mount on the vehicle and will transmit its signal to a hand-held device and alert the motor-pool soldier of coating damage or deterioration so that preventative maintenance can be scheduled to forestall serious structural damage due to the corrosion. The result will be decreased maintenance and replacement costs with increased readiness and reliability.

LUNA INNOVATIONS, INC.
2851 Commerce Street
Blacksburg, VA 24060
Phone:
PI:
Topic#:
(540) 552-5128
Fritz Friedersdorf
OSD 04-C14      Awarded: 10DEC04
Title:Ultra low cost wireless corrosion sensor for ground vehicles
Abstract:The Army spends an estimated $2 billion to $2.5 billion per year addressing corrosion-related issues with Army ground vehicles. Corrosion also has a significant impact on force readiness. Army ground vehicles that require corrosion-related repairs are typically out of service for many months. Corrosion has also been shown to dramatically shorten vehicle life. Low cost and easy-to-use corrosion/corrosivity sensors offer the potential to dramatically reduce vehicle life cycle costs and improve readiness. Knowledge of corrosion state and environment enables more effective corrosion mitigation and prediction. To address this critical defense need, Luna Innovations proposes to develop a corrosion/corrosivity sensor system specifically designed for the rigorous operational environment of Army ground vehicles. The proposed system will be ultra low cost, passive and wireless. It will be based on commercially available technology, will not require wired or battery power, and will enable remote interrogation and placement where needed around the vehicle. Luna has assembled the highly qualified, multidisciplinary team required for a successful program and has a history of bringing novel research from the laboratory to commercial markets.

PERFORMANCE POLYMER SOLUTIONS, INC.
91 Westpark Road
Centerville, OH 45459
Phone:
PI:
Topic#:
(937) 298-3713
Dr. David B. Curliss
OSD 04-C15      Awarded: 01FEB05
Title:GALVANIC CORROSION MECHANISMS ANALYSIS AND MODELING FOR F-35 GRAPHITE/BMI COMPOSITE-METALLIC AIRFRAME JOINTS
Abstract:The P2SI team objective in this proposed research effort is to develop an inherently corrosion resistant composite/metallic joint design. As coatings and sealants deteriorate in service the joint will be inherently corrosion resistant. This will be achieved through a thorough understanding of how the fundamentals of galvanic corrosion relate to corrosion susceptibility of the F-35's composite-metal joints. In this effort, we will experimentally validate our approach using parameters from the F-35 baseline design. The P2SI approach will identify composite-metallic joint configuration dependent and independent variables that directly affect the potential for galvanic corrosion. We will investigate the corrosion rate and effect of corrosion on joint integrity and strength. This will enable us to establish allowable tolerances for design and manufacturing that will protect joints from catastrophic galvanic corrosion failure, even in the event of coating and sealant deterioration in service. In Phase I, multi-variable regression analysis will be performed on the data to model observed effects. We will perform environmental exposure, detailed corrosion and corrosion rate analysis, and residual mechanical property measurements on F-35 joint-based specimens. This approach will ensure maximum relevance of the data and modeling performed under this effort towards state-of-the-art airframe structural design and analysis.

CAPE COD RESEARCH, INC.
19 Research Road
East Falmouth, MA 02536
Phone:
PI:
Topic#:
(508) 540-4400
Mr. Francis L. Keohan
OSD 04-C16      Awarded: 13JAN05
Title:New Corrosion Inhibiting Cleaning System for Aluminum Alloys
Abstract:Precoat surface cleaning of aluminum alloys is critical for removing common surface contaminants such as loose metal oxides, oils, and dirt that can impede wetting and adhesion of subsequently applied coatings. Many caustic cleaning processes cause matrix dealloying/redeposition of copper, which often results in copper on the aluminum alloy surface and localized corrosion initiation. A new cleaning process is proposed that effectively removes the surface contaminants and poorly adhered oxides while minimizing the corrosion-inducing redeposition of copper smut. The objective of the Phase I program is to identify candidate metal pretreatment systems which meet the goals of low toxicity, simple application, effective surface cleaning, passivation and copper-redeposition prevention for enhancing corrosion inhibition. A novel combination of surface-active compounds, inhibitors, and anti metal redeposition agents will be used to formulate the new aqueous-based cleaning systems. These pretreatment systems and suitable controls will be tested on common aircraft aluminum alloys for cleaning efficiency, inherent corrosion inhibition by potentiodynamic electrochemical analysis, compatibility with conversion coating application and paint adhesion. The costs, hazards, and environmental fate of effluents produced by the new cleaning processes will be estimated and used in the system design.

LUNA INNOVATIONS, INC.
2851 Commerce Street
Blacksburg, VA 24060
Phone:
PI:
Topic#:
(540) 552-5128
Kevin Cooper
OSD 04-C16      Awarded: 19JAN05
Title:Advanced Aluminum Alloy Cleaning Methods for Improved Corrosion Resistance
Abstract:The objective of the program is to demonstrate the feasibility of developing environmentally acceptable surface cleaning methods that increase the corrosion resistance of aircraft aluminum alloys. Existing specified cleaning processes degrade the corrosion properties of high-strength aluminum alloys due to formation of a copper-rich surface. Luna Innovations, Inc. will develop multiple cleaning environments and processes and quantitatively evaluate their impact on corrosion behavior of aircraft aluminum alloys. The Phase I will focus on demonstrating the selective removal and gettering, to prevent deposition, of alloying elements that degrade corrosion resistance, in particular copper. Chemical, mechanical and electrochemical means will be examined as methods to control the amount and electrochemical activity of copper and copper-bearing intermetallics on the cleaned surface. State-of-the-art electrochemical techniques will be used to quantify metrics of corrosion susceptibility that will facilitate objective evaluation of the various cleaning method. Evaluation will be done in comparison to a control cleaning method based on existing specified treatments.

NOMADICS, INC.
1024 S. Innovation Way
Stillwater, OK 74074
Phone:
PI:
Topic#:
(405) 372-9535
Dr. Arif Mamedov
OSD 04-C16      Awarded: 19JAN05
Title:Cleaning Solutions That Improve Corrosion Resistance of Aluminum Alloys
Abstract:Surface cleaning is extremely important in that it removes common surface contaminants such as loose metal oxides, oils, dirt, etc. that have deleterious effects on the wetting and adhesion of subsequently applied coatings. However, during the cleaning process, matrix dealloying and redeposition of copper, which have been shown to be sites for corrosion initiation. Nomadics will use custom synthesized chelating additives, which have high affinity to copper ions, to prevent the formation of copper "islands." This will reduce corrosion. The process will be easy to apply without undesirable environmental impact.

TDA RESEARCH, INC.
12345 W. 52nd Ave.
Wheat Ridge, CO 80033
Phone:
PI:
Topic#:
(303) 940-5380
Dr. Jeannine Elliott
OSD 04-C16      Awarded: 21JAN05
Title:Improved Aluminum Cleaning Method to Prevent Copper Enrichment
Abstract:Since pure aluminum is soft and has only moderate strength, aluminum alloys are used for aerospace and other structural applications. However, the copper in these alloys significantly reduces the corrosion resistance of the aluminum. The standard pretreatment used to clean aluminum alloys before painting or coating enriches the surface of the aluminum with copper, creating sites for corrosion. An ideal aluminum cleaning procedure would degrease and deoxide the surface without dealloying the copper and allowing it to redeposit on the surface. In this Phase I proposal TDA will develop an additive for surface pretreatment cleaners that prevents copper enrichment during pretreatment of high strength aluminum alloys.

GATR TECHNOLOGIES
130 Lakeshore Drive
Madison, AL 35758
Phone:
PI:
Topic#:
(256) 461-8684
Mr. Paul A. Gierow
OSD 04-C17      Awarded: 10FEB05
Title:Novel CORIN Materials and Advanced Coating Processes for Space Environment Polybenzoxazole Protection
Abstract:Deployable space structures are becoming increasingly important assets for use in the battlefield. Communications, global positioning, unmanned air vehicles and tracking and surveillance of enemy troops are creating an enormous demand for space borne assets. Structures that can package efficiently meet many of the needs of creating larger apertures for the high bandwidth military missions. We propose to demonstrate a novel high temperature dyed Colorless Organic/Inorganic Nanocomposite polyimide (CORIN) material. The material will be synthesized for coating PBO fibers and sheets to prevent VUV, UV, and AO degradation. The base polyimide has been successfully flight qualified, and transitioned for products on NASA, DoD and commercial satellite communications structures. Phase I results will be to demonstrate a scaleable process for applying coating materials to Polybenzoxazole fibers. Mechanical quantification of the material coating will be performed to demonstrate the adhesion of the polymer to the fiber during repeated cyclic stress and thermal loading. A key aspect of the proposed effort is transition of the coating process from a laboratory scale to production oriented processes. Our process will be demonstrated in Phase I for coating fiber and yarn materials to be scaled to production level processes in Phase II.

TRITON SYSTEMS, INC.
200 TURNPIKE ROAD
Chelmsford, MA 01824
Phone:
PI:
Topic#:
(978) 250-4200
Dr. Arthur Gavrin
OSD 04-C17      Awarded: 04FEB05
Title:Space Durable Coatings for PBO(1000-574)
Abstract:There exists a need to identify and develop various coatings that can be used in the protection of polybenzoxazole (PBO) materials. PBO has exceptionally good strength-to-weight ratio and temperature stability. PBO fibers have been identified for a variety of space applications. These applications consist of, but are not limited to, power generation, orbital maneuvering, and planetary exploration. For example, momentum exchange (MXER) tethers utilize the physics of momentum transfer to catapult a payload out of the Earth's gravity well. This tether system requires space durable, high strength-to-weight ratio fibers. Tether materials-related advances are primary for improving the operation and lifetime of the propulsion system. Critical materials properties in need of improvement include increases in tensile strength, electrical conductivity, shock resistance, continued flexibility during exposure to an environment rich in radiation and energetic atomic oxygen. PBO films and solids have been proposed for use as lightweight structural materials for satellite housing and other spacecraft systems. In this program, Triton Systems will develop multiple space durable protective coatings for PBO.

ULTRAMET
12173 Montague Street
Pacoima, CA 91331
Phone:
PI:
Topic#:
(818) 899-0236
Dr. Jason R. Babcock
OSD 04-C17      Awarded: 04FEB05
Title:Novel Low Temperature Coating Method for Environment-Resistant Coatings on Polymers
Abstract:Polybenzoxazole polymers, including polyphenylenebenzobisoxazole (PBO) in particular, are under development for use in a wide variety of aerospace applications due to their remarkable tensile strength, modulus, and flame resistance. These materials are of particular interest due to their high strength-to-weight ratio, which allows for a dramatic weight savings when replacing conventional structures. This is particularly significant for in-space applications such as satellites. Satellite components are exposed to potentially damaging impingements, such as ultraviolet (UV) light, atomic oxygen, and fast-moving particles. There is a need for PBO coatings that can increase the functional lifetime of the polymer in the harsh space environment. In ongoing, complementary work, Ultramet introduced a unique and innovative chemical vapor deposition (CVD) technology that relies upon UV activation of the CVD process rather than conventional thermal activation. This low temperature deposition route is ideally suited for coating substrates with relatively low thermal stability, such as PBO. The objective of the proposed project is to assess the viability of this innovative process for scaleable production of coatings that could be effectively used for government and commercial satellite components.

ADVANCED THERMAL TECHNOLOGIES, LLC
91 South St.
Upton, MA 01568
Phone:
PI:
Topic#:
(508) 529-4413
Dr. James W. Connell
OSD 04-EP1      Awarded: 09DEC04
Title:Advance Cooling Designs for High Temperature Transformers and Inductors for Power Electronics
Abstract:As a result of continuing advances in magnetic materials, compression of circuit physical architecture, increase in magnetic component packaging density and faster switching speed, the heat dissipation rate of next generation military power converter systems will require operation at significantly higher heat flux levels than current power converters. The goal of this SBIR Phase I program is the development of novel magnetic materials with optimal characteristics to meet the required high temperature and electrical operating requirements for military power converters. A further goal of this program is the development of a thermal management approach that utilizes a phase change process coupled with the use of a unique high thermal conductivity 3-D carbon structure to meet the power converter heat dissipation requirements. The design of the 3-D carbon structure would be engineered to provide a high surface area to volume ratio heat exchanger element that would enable a compact, light-weight highly effective heat exchanger device. Further, the design of the 3-D carbon structure will ensure that the local heat flux within the active heat exchange device is sufficient to maintain the power converter operation for continuous and pulse power operation. The proposed thermal management concept will be capable of maintaining the magnetic components at or below their required maximum operating temperature, thus, ensuring system reliability and life.

PRECISION MAGNETIC BEARING SYSTEMS, INC.
25 Walker Way Sec. 2A
Albany, NY 12205
Phone:
PI:
Topic#:
(518) 218-0477
Dr. Dantam K. Rao
OSD 04-EP1      Awarded: 09DEC04
Title:Power Dense High Temperature Passives
Abstract:The goal of this project is to develop Power-Dense Passives that can increase the Power Density to 25 kW/liter and facilitate operation at high ambient temperature of up to 150 C. The passives will consist of a core, winding and built-in advanced cooling system. Existing inductor and transformer configurations will be reviewed and a trade study will be conducted to identify an innovative core configuration. A detailed design of a prototype passive will be conducted to quantify the power density. A core material that offers lowest core loss will be chosen and the core will be configured to provide an easy path for flux and a high resistance path for eddy currents. The winding will be designed to minimize ac losses and will use high temperature insulation materials. The advanced cooling system will be designed to cool both the winding and the core uniformly and offer low thermal resistance. A preliminary layout of a passive is the end result of this effort

TECHNOLOGY ASSESSMENT & TRANSFER, INC.
133 Defense Highway, Suite 212
Annapolis, MD 21401
Phone:
PI:
Topic#:
(410) 224-3710
Mr. Walter Zimbeck
OSD 04-EP1      Awarded: 21DEC04
Title:Internally Cooled Magnetic Cores
Abstract:Technology Assessment and Transfer Inc. (TA&T) proposes fabricating high power magnetic cores with integrated fluidic cooling channels to meet the requirements of emerging inductors and transformers for power electronics applications. TA&T has developed processes for fabricating monolithic ceramic components with complex geometry, including internal cavities and channels that cannot be fabricated using conventional processing techniques. This capability will be applied to the fabrication of ferrite cores with internal cooling channels for improved heat dissipation. Two novel fabrication approaches will be evaluated in Phase I. The first is known as ceramic stereolithography (CSL), and is an automated, layered manufacturing process that enables net shape, monolithic ceramics with complex geometry. The second approach, called gel casting, is a thermally cured net shape molding process that utilizes sacrificial structure to form the internal geometry.

CERAMATEC, INC.
2425 South 900 West
Salt Lake City, UT 84119
Phone:
PI:
Topic#:
(801) 978-2142
Mr. Shekar Balagopal
OSD 04-EP2      Awarded: 21DEC04
Title:Lithium Conducting Ceramic Membrane Electrolytes for Lithium Batteries
Abstract:New nano-structured electrodes and a novel lithium-ion conducting solid ceramic electrolyte that can potentially double the energy density of the existing battery systems is proposed. The solid electrolyte offers excellent chemical stability to corrosive lithium metal and the conductivity approaches 10-2 S/cm and 10-4 S/cm respectively in aqueous and organic electrolytes respectively. The materials used in the proposed battery are abundant, inexpensive and environmentally benign. The combined objective of Phase I and Phase II effort is to develop LiSICON electrolyte and integrate with a metallic Li anode and a high capacity, cathode material based on either (a) oxygen from air or (b) nano-structured V2O5 to realize high energy density batteries. The proposed "lithium anode- LiSICON electrolyte - oxygen (or V2O5) cathode" battery can potentially meet the high energy requirement of military equipment and vehicles.

MATERIALS & ELECTROCHEMICAL RESEARCH (MER) CORP.
7960 S. Kolb Rd.
Tucson, AZ 85706
Phone:
PI:
Topic#:
(520) 574-1980
Dr. Sorhab Hossain
OSD 04-EP2      Awarded: 29DEC04
Title:High Energy Density, Fast Charge Lithium-ion Batteries
Abstract:The need for a high specific energy, fast charge battery for the U. S. army is recognized. The proposed Phase I program addresses to investigate the feasibility of developing prototypes 7.5 Ah lithium-ion cells having specific energy >210 Wh/kg which will be used as `building blocks' for the development of BB-2590 ibatteries in Phase II.A novel electrochemical couple is proposed for the development of a fast charge,high specific energy lithium-ion battery system. The proposed anode material delivers 50% higher practical capacity than the state-of-the-art carbon anode materials. Several prototype lithium-ion cells will be developed and their performance will be evaluated to demonstrate the proof-of-concept.

MAXPOWER, INC.
220 Stahl Road
Harleysville, PA 19438
Phone:
PI:
Topic#:
(215) 513-4230
Dr. Mark Salomon
OSD 04-EP2      Awarded: 23DEC04
Title:New High Energy Density Li/Li-Ion Batteries
Abstract:MaxPower's Phase I program will involve development of new cathode materials and new electrolyte solutions to significantly improve gravimetric energy densities and rate capabilities. With these objectives in mind, the following details the approaches MaxPower will take in its Phase I program. To improve gravimetric and volumetric energy densities and rate capabilities, the Phase I program will synthesize and optimize the performance of 5 V (vs. Li/Li+) cathode materials. Nano cathode materials will be developed. To improve capacity retention upon extended cycling of the 5 V cathode materials, MaxPower will develop new electrolyte solutions which are stable to at least 5 V vs. Li/Li+.

NANOMAT, INC.
1061 Main Street, Building #1 - Drawer #18
North Huntingdon, PA 15642
Phone:
PI:
Topic#:
(724) 978-2188
Dr. Pramod Sharma
OSD 04-EP2      Awarded: 16DEC04
Title:Nanosize Cathode Materials for high Performance Li- Ion Rechargeable Batteries
Abstract:The widespread use of battery is severely hampered by low energy density and poor performance of cathode materials of Li-ion battery due to the micron size particles, small surface area, unstable structure during cycle, inadequate mechanical strength, costly precursors, temperature unstable low ionic conductivity etc. The goal of this project is to develop nano-structured cathode material by a novel method that will result in a high energy density of batteries for electric vehicle and other applications. In this phase I effort, to mitigate the deficiencies of the currently available cathode materials, a nanosize Li[NixCo1-2xMnX]O2 cathode materials will be developed. This cathode material has an excellent storage capability. Li[NixCo1-2xMnX]O2 material will be rigorously tested for their electrochemical, thermal, physical and structural properties to insure that it possess the requisite performance characteristics and high energy density at least an improvement of 2X. In Phase II, further testing and development of these cathode materials will be conducted. A prototype of battery with be design with high energy density. In Phase II, a prototype will also be manufactured for field-testing under actual conditions.

NEI CORP.
Suite 102/103, 201 Circle Drive
Piscataway, NJ 08854
Phone:
PI:
Topic#:
(732) 868-1906
Dr. Amit Singhal
OSD 04-EP2      Awarded: 20DEC04
Title:High Energy Density Li-ion Batteries With Good Low Temperature Performance
Abstract:High energy density Li-ion batteries that can operate over a wide temperature range are needed in a variety of military, space and commercial applications. The specific energy of Li-ion batteries can be enhanced by utilizing new cathode materials that have significantly higher energy density than that of state-of-the-art LiCoO2. Low temperature performance of Li-ion batteries can be improved by reducing the electrolyte resistance and enhancing the mass transfer across the electrode/electrolyte interface. This can be accomplished by raising the ionic conductivity of the electrolyte and reducing the size of electrode particles, respectively. The proposed program focuses on developing novel nanostructured cathode materials with an energy density of ~ 800 Wh/kg, which is almost 50% higher than that of the practical energy density of LiCoO2. Working in collaboration with a leading developer of Li-ion batteries, in Phase I, we will demonstrate that it is possible to produce a stable high energy density nanostructured cathode by controlling the structure and composition of nanoparticles. As part of the Phase I work, a low temperature electrolyte will be used in Li-test cells to evaluate the electrochemical performance of nanostructured cathodes at sub-zero temperatures. In Phase II, prototype batteries will be fabricated and tested for performance, along with optimization and scaling of the synthesis process for producing electrode nanoparticles.

AGILTRON CORP.
220 Ballardvale St., Suite D
Wilmington, MA 01887
Phone:
PI:
Topic#:
(978) 694-1006
Dr. Jack Salerno
OSD 04-EP3      Awarded: 13DEC04
Title:Nanostructure-Enhanced Bulk Thermoelectric Materials
Abstract:The use of thermoelectric devices as alternative energy sources has been investigated with limited success. Manufacturing costs and limited power generation efficiency have prevented the economical, large-scale production and use of the thermoelectric devices as a viable alternative energy source. Agiltron has proposed an innovative nanostructure-enhanced thermoelectric material that will integrate the synthesis of PbSe nanowires and the fabrication of nanocomposite-enhanced bulk thermoelectric materials. The proposed technologies will include single-phase, highly-crystalline, surface-clean and diameter-controlled PbSe nanowires fabrication; orientation, and densification with ball-milled submicrometer-sized powder of bulk thermoelectric material into nanocomposite-enhanced thermoelectric material through a hotpress technique. The thermoelectric figure of merit of this new nano-composite is predicted to reach ZT = 3 at 300K. This innovative thermoelectric material will have immense application potentials in power generation, energy harvesting, and solid-state cooling and refrigeration.

EVIDENT TECHNOLOGIES, INC.
216 River Street, Suite 200
Troy, NY 12180
Phone:
PI:
Topic#:
(518) 276-3444
Ms. Margaret Hines
OSD 04-EP3      Awarded: 13DEC04
Title:High Performance Thermoelectric Materials Using Solution Phase Synthesis of Narrow Bandgap Core/Shell Quantum Dots Deposited Into Colloid Crystal Thin Films
Abstract:Evident Technologies, Inc. intends on using its core competency in quantum dot synthesis, quantum dot surface modification and quantum dot composites to create cost effective, high ZT thermoelectric thin films that can be deposited onto inexpensive flexible substrates. In the Phase I demonstration project Lead Selenide nanocrystals with a 1-2nm thick shell of PbS will be synthesized using proprietary solution phase synthesis techniques. These quantum dots, initially suspended in solution, will then be self assembled into a colloid crystal on substrate using surface modification and controlled solvent evaporation. Finally the PbS shells surrounding the PbSe quantum dot cores will be thermally fused resulting in a thin film structure having colosely spaced PbSe quantum dots suspending in a PbS matrix.

LUTRONICS
28 Ruthellen Rd.
Chelmsford, MA 01824
Phone:
PI:
Topic#:
(978) 387-9685
Dr. Yalin Lu
OSD 04-EP3      Awarded: 13DEC04
Title:Novel Nanostructure-Enhanced Approach for Bulk Thermoelectric Materials
Abstract:Lutronics proposes a unique combination of an innovative multiple shallow quantum well concept, a new nano-approach, and a unique bulk material processing method, with which great breakthroughs in thermo-electrical figure-of-merit can be expected. The Phase I was intended for proving the proposed concept. Success of the Phase I research will lay down a solid foundation for the following Phase II researches.

METAMATERIA PARTNERS LLC
1275 Kinnear Rd.
Columbus, OH 43212
Phone:
PI:
Topic#:
(614) 340-1690
Dr. Suvankar Sengupta
OSD 04-EP3      Awarded: 13DEC04
Title:Nanostructure-Enhanced Bulk Thermoelectric Materials
Abstract:Significant improvement in the ZT (figure of merit) has been recently been reported in thin film thermoelectric materials. These improvements were achieved by taking the advantage of low dimensionality in PbTe-based quantum well and quantum dot systems prepared by MBE and in BiTe-SbTe quantum well systems prepared by MOCVD. However, to become commercially viable new low-cost processing routes are needed for preparing bulk materials that contains nanostructured, thermoelectric active components. The proposed program focuses on development of a nanocomposite thermoelectric material composed of nanostructured "core-shell" particulates. In Phase I, "core-shell" nanostructure PbTe-PbSe will be developed by using a solution based technique, consolidated using colloidal processing techniques and then densified using high energy compaction. The nanocomposite bulk samples for evaluated by Hi-Z, a thermoelectric manufacturer.

NANOHMICS, INC.
6201 East Oltorf St., Suite 100
Austin, TX 78741
Phone:
PI:
Topic#:
(512) 389-9990
Dr. Steve Savoy
OSD 04-EP3      Awarded: 13DEC04
Title:Nanostructure-Enhanced Bulk Thermoelectric Materials
Abstract:Compact, solid-state thermoelectric devices are now widely used for both cooling and power generation. These highly reliable devices have no moving parts, operate around room temperature, and are easily integrated into thermal systems. Despite these advantages, engineering applications have been limited by the relatively low intrinsic power conversion efficiency of the semiconductor material comprising the devices. Engineered, nanometer-scale semiconductor materials are now being developed to increase the thermoelectric efficiency. Much larger enhancements in thermoelectric efficiency are predicted in true quantum confined systems since this confinement produces peaks in the density of states. Accordingly, nanometer-sized spheres or rods should offer the highest increase in Seebeck coefficient. It should be possible to fabricate a composite material based on semiconducting nanoparticles that exhibits enhanced thermoelectric efficiency using high electrical/thermal conductivity ratio materials (e.g. conducting polymers) to provide a means for intergrain connectivity between the nanoparticles. To this end, Nanohmics and Drs. Kevin Stokes and Jiye Fang of the Advanced Materials Research Institute (AMRI) at the University of New Orleans propose to develop bulk thermoelectric composites consisting of organized assemblies of thermoelectric nanomaterials and conducting polythiophenes using an automated assembly process.

NANOLAB, INC.
55 Chapel St
Newton, MA 02458
Phone:
PI:
Topic#:
(617) 581-6747
Mr. David L. Carnahan
OSD 04-EP3      Awarded: 13DEC04
Title:Nanostructure-Enhanced Bulk Thermoelectric Materials
Abstract:NanoLab plans to synthesize nanoparticles of Sb2Te3, Bi2Te3,Bi2Se3, silicon and germanium using established and experimental techniques that are applicable to large scale synthesis. We will investigate the rapid consolidation of these nanoparticles to form nanocomposites of Si-Ge, Bi2Te3-Sb2Te3 (p-type) and Bi2Te3-Bi2Se3 (n-type), and test their thermoelectric properties.

TELLUREX CORP.
1248 Hastings St.
Traverse City, MI 49686
Phone:
PI:
Topic#:
(231) 947-0110
Mr. Charles J. Cauchy
OSD 04-EP3      Awarded: 13DEC04
Title:Nanostructure-Enhanced Bulk Thermoelectric Materials
Abstract:The objective of this proposal is to develop and implement methodologies for new bulk thermoelectric materials that incorporate nanostructural elements to significantly increase the thermoelectric figure of merit, ZT, by way of phonon boundary scattering providing enhanced fuel economy via waste-heat to electrical energy conversion as well as provide stand-alone power from either intentional fuel sources or naturally occurring heat harvesting circumstances. Three primary methods will be used to develop nanostructures within a target thermoelectric alloy (AgPbmSbTe2+m) with the goal of developing a commercially realizable bulk material methodology resulting in high ZT thermoelectric devices. The unique cubic AgPbmSbTe2+m (LAST) structural identity can be exploited to produce nanostructural components that will act as phonon scattering sites within the bulk material. Tellurex's continuing work on the LAST system indicates that structural grain size reduction may be brought to nanoscale through rapid quenching and advanced mechanical powder processing techniques. A scaled sintering regimen will also be developed and employed to induce nanoscale boundary growth providing phonon boundary scattering. These processes will be used singularly and in combined strategies to determine the method resulting in the highest ZT and provide the focus for Phase II and Phase III development.

AEROVIRONMENT, INC.
825 S. Myrtle Avenue
Monrovia, CA 91016
Phone:
PI:
Topic#:
(626) 357-9983
Mr. Wally Rippel
OSD 04-EP5      Awarded: 03DEC04
Title:Lightweight Power Transformer for Shipboard Electrical Power Distribution Systems
Abstract:As with most forms of transportation, ships have weight and volume constraints relative to operational equipment. Conventional transformers, in use to convert high voltage electric power to lower voltages and vice versa, are both heavy and big. With recent advances in semiconductor devices and digital control, "Electronic Transformers" can replace conventional transformers while providing a factor of three weight and size reductions. Electronic Transformers can potentially also provide side benefits such as voltage regulation, power factor correction, VAR compensation, and low harmonics. The proposed Phase I effort will investigate the feasibility of developing such Electronic Transformers. Conventional transformers have the advantage of relatively low cost and high full-load efficiency. Thus, the value of the weight and size reductions, and power system benefits that the Electronic Transformers provide, will have to offset lower efficiencies and potentially higher costs. Systems analyses and trade studies may show that Electronic Transformers compete very well. AeroVironment will overcome the many technical challenges leveraging experience from recent transformer/inductor development projects and digital control development projects. By demonstrating feasibility, we will help enable the Navy to improve shipboard electrical systems operations, while reducing electrical equipment weight and volume claims.

AMERICAN SUPERCONDUCTOR
Two Technology Drive
Westborough, MA 01581
Phone:
PI:
Topic#:
(262) 901-6007
Mr. David Gritter
OSD 04-EP5      Awarded: 09DEC04
Title:Lightweight Power Transformer for Shipboard Electrical Power Distribution Systems
Abstract:A topology for a medium voltage to low voltage 3-phase power converter is proposed. It consists of a clean power rectifier followed by multiple isolated DC to DC converters using commercially available high frequency transformers with very low core losses when driven by a quasi-resonant inverter operating in the 20 to 50 kHz range. The DC to DC input DC busses are placed in series, while the outputs are in parallel to effect the reduction in voltage from medium to low. Finally a DC to AC inverter re-constructs a 3-phase voltage, which after filtering, provides high quality power for low voltage loads. This proposal defines development efforts to identify the appropriate rectifier topology if clean input currents are required, to build and test a breadboard high frequency transformer, and to refine the design of the output DC to AC inverter and filters.

ENGINEERING MATTERS, INC.
375 Elliot Street, Suite 130K
Newton, MA 02464
Phone:
PI:
Topic#:
(617) 965-8974
Dr. David Cope
OSD 04-EP5      Awarded: 03DEC04
Title:Lightweight Power Transformer for Shipboard Electrical Power Distribution Systems
Abstract:The objective is to develop lightweight voltage step-down equipment to be used in vehicle power distribution systems, with particular emphasis on the DD(X) and CVN(X) programs. Conventional 60Hz power distribution transformers are large and heavy. The Navy seeks a smaller and lighter replacement technology. The voltage level and operating frequency drive the physical size of a power transformer. High voltage and low frequency yield high magnetic flux and necessitate a large transformer core. Engineering Matters proposes to design, simulate, fabricate and build a transformer-isolated high-frequency switch-mode power supply to replace existing low-frequency transformers. Engineering Matters has already developed a high voltage, high frequency solid-state switch. This switch will enable the power supply to operate directly from primary shipboard distribution voltage (13.8kV) at frequencies above 5kHz. At high frequency, the size of the transformer will be greatly reduced. The core design will be optimized for volume savings, with material to be selected from ferrite, amorphous metal, and advanced iron-based magnetic alloys. The switching power supply will also feature voltage regulation and a high power factor.

IAP RESEARCH, INC.
2763 Culver Avenue
Dayton, OH 45429
Phone:
PI:
Topic#:
(937) 297-3153
Mr. Antonios Challita
OSD 04-EP5      Awarded: 02DEC04
Title:Lightweight Transformer Replacement
Abstract:We propose to develop a semiconductor-based transformer for medium voltage (4160V or 13.8kV) to low voltage (450V) step down applications on ships. These transformers provide ship service power and are used on all ships where primary generation and distribution is medium voltage. Our concept uses high frequency semiconductor switching to reduce the mass and size of these transformers by a factor of 5 to 10.

PRINCETON POWER SYSTEMS, INC.
501 Forrestal Road Suite 211, Forrestal Campus
Princeton, NJ 08540
Phone:
PI:
Topic#:
(609) 258-5994
Mr. Mark Holveck
OSD 04-EP5      Awarded: 02DEC04
Title:Unique AC-link Power Converter Design with a Small, Lightweight, High-Frequency Internal Transformer
Abstract:In Phase I, we propose to design a 300kW DC-DC converter for hybrid vehicles that operates at 92% efficiency, with 100øC coolant inlet temperature, and fits within 50L (6kW/L). Transitioning to the use of Silicon Carbide switching technology when it becomes available should allow increases in power density to 8kW/L. Our unique innovation is using the AC-link power conversion technology, which provides extremely low switching losses and minimal component count. AC-link is a softswitching technology, which minimizes switching losses resulting in reduced active switch and thermal management requirements. AC-link is currently being used in a similar project to build a 250kW power-dense DC-DC converter for the Air Force's Active Denial Technology; these efforts will be leveraged for this project. We will also construct a 10kW bench-scale unit in Phase I to prove the feasibility of the system. In Phase II, we will develop and deliver a 300kW converter meeting the design criteria specified. Dr. Rudy Limpaecher at SAIC and Dr. Tony Mavretic at Siat of Boston Inc. will consult on the project. We already have outside investment groups interested in investing in the Phase III manufacturing effort.

AMERICAN SUPERCONDUCTOR
Two Technology Drive
Westborough, MA 01581
Phone:
PI:
Topic#:
(508) 621-4243
Mr. John Voccio
OSD 04-EP6      Awarded: 24JAN05
Title:Superconducting Developments for Compact Power and Energy Systems
Abstract:In recent years, there have been significant advances in YBCO coated conductor development. AMSC reported achieving electrical performance levels of 330 Amps, 10 percent above the commercial threshold performance level of 300 Amps set by the U.S. Department of Energy (DOE) for 2G HTS wires. Also, high performance reults were reported on greater than 30-m lengths - triple the length of its previously reported results. In addition, some preliminary work has been performed by MIT and DOE/ORNL on the quench stability in these tapes, primarily for cable applications, primarily for cable applications. However, thre has been little work performed on YBCO coils. Therefore, the purpose of this SBIR effort is to focus on issues related to the design, fabrication and testing of YBCO coils. By studying and understanding such issues as YBCO coil thermal and mechanical properties and selecting preferred methods of insulation, advances in YBCO coil design can be achieved. Furthermore, as progress is made in designing and fabricating low-loss, ac conductors from this material, it is expected that under Phase II, coils can be designed and tested for either a prototype transformer or stator winding.

CRYOMAGNETICS, INC.
1006 Alvin Weinberg Dr.
Oak Ridge, TN 37830
Phone:
PI:
Topic#:
(865) 482-9551
Dr. Earle Burkhardt
OSD 04-EP6      Awarded: 10JAN05
Title:Superconducting Developments for Compact Power and Energy Systems
Abstract:Superconducting coils are capable of storing considerable amounts of energy. Should a coil quench, due to overheating or exceeding the critical field or current carrying ability of the wire, the stored energy in the coil must be dissipated safely - without endangering personnel or damaging the coil or control systems. In any superconducting coil design, it is essential to design and build the system such that the limits of the materials involved are not exceeded. High temperature superconductors (HTS) are relatively new to applications in magnets and coils, but are rapidly growing in use thanks to advances in conductor performance and availability. However, not much is known currently concerning the quench protection design limits of the materials. Thus far, quench protection in high temperature superconducting coils has been largely overlooked. This has mainly been due to the fact that HTS materials have higher heat capacities at their operating points, and are often difficult to quench. Unfortunately this high heat capacity also creates slow propagation velocities which can cause catastrophic damage to the HTS. New methods for quench protection in HTS coils will be analyzed via computer simulation.

HYPER TECH RESEARCH, INC.
110 E. Canal St.
Troy, OH 45373
Phone:
PI:
Topic#:
(937) 332-0348
Mr. Michael Tomsic
OSD 04-EP6      Awarded: 25JAN05
Title:YBCO Coated Conductors and Coils for Rotor Applications
Abstract:The Air Force is currently pursuing the development of high temperature superconducting generators. Coated YBCO superconductor tape is a strong candidate to enable this application. These generators for the Air Force will operate up to several hundred hertz. This SBIR Phase I investigates construction of racetrack rotor coils with standard and patterned YBCO coated conductor tapes. This Phase I will investigate winding techniques, stress, and insulation to fabricate racetrack coils. This information will enable us to model, design, and develop larger YBCO racetrack rotor coils for demonstration generators.

HYPER TECH RESEARCH, INC.
110 E. Canal St.
Troy, OH 45373
Phone:
PI:
Topic#:
(937) 332-0348
Mr. Michael Tomsic
OSD 04-EP6      Awarded: 24JAN05
Title:Magnesium Diboride (MgB2) Superconducting Coils for Gyrotron Magnets
Abstract:The Air Force is currently pursuing the development of directed weapons using high frequency gyrotrons. Present systems use coils made with niobium titanium superconducting wire operating at 4 K with a cryocooler. Light weight magnesium diboride superconductor wire offers the potential of the required magnetic field but will operate at higher temperature of 10-25 K, and be a much lighter weight superconductor. Thus there is the potential to reduce the size and weight of the gyrotron magnet and cryocooler for airborne applications. This SBIR Phase I will demonstrate a sub-size solenoid gyrotron magnet with magnesium diboride superconducting wire, and determine what weight and size reductions could be made for a full size magnesium diboride gryotron magnet and cryocooler.

METAL OXIDE TECHNOLOGIES, INC.
8807 Emmott Rd., Suite 100
Houston, TX 77040
Phone:
PI:
Topic#:
(834) 243-0917
Dr. Alexandre Molodyk
OSD 04-EP6      Awarded: 11FEB05
Title:Enhancement of YBCO Coated Conductor Performance by Chemical Pinning
Abstract:MetOx propriatary MOCVD deposition technology makes possible the prospect of chemical pinning to increase the superconducting properties of YBCO HTS films on textured substrates. Program objectives are to create pinning sites by chemical modification of process parameters and measure the properties of the YBCO films.

STRUCTURED MATERIALS INDUSTRIES
201 Circle Drive North, Unit # 102
Piscataway, NJ 08854
Phone:
PI:
Topic#:
(732) 302-9274
Dr. Nick M. Sbrockey
OSD 04-EP6      Awarded: 28JAN05
Title:Effective Flux Pinning In YBa2Cu3Ox Coated Conductors by Continuous MOCVD
Abstract:In this SBIR Phase I effort, Structured Materials Industries, Inc., (SMI) will develop process and hardware technology for continuous production of YBa2Cu3Ox (YBCO) coated conductors with a nano-engineered array of non-superconducting particles. These non-superconducting precipitates will act as highly effective flux pinning centers, and enable superconducting tapes with enhanced critical current in the presence of magnetic fields. The enhanced YBCO coated conductors will enable superconducting components for compact, light-weight, AC power systems for airborne weapons systems, as well as a variety of other military and commercial power applications.

TAI-YANG RESEARCH CORP.
9112 Farrell Park Lane
Knoxville, TN 37922
Phone:
PI:
Topic#:
(302) 379-2712
Ms. Ann T. Shih
OSD 04-EP6      Awarded: 25JAN05
Title:Superconducting Developments for Compact Power and Energy Systems
Abstract:Tai-Yang Research Company of Tennessee in cooperation with the Francis Bitter National Magnet Laboratory, propose to design, analyze, and test a novel method to enhance the quench stability and thermal stabilization of high temperature superconducting YBCO coils. The proposed method utilizes a revolutionary type material with unsurpassed thermal conductivity.

UES, INC.
4401 Dayton-Xenia Road
Dayton, OH 45432
Phone:
PI:
Topic#:
(937) 426-6900
Dr. Yongli Xu
OSD 04-EP6      Awarded: 13JAN05
Title:Development of High Jc Thick YBCO Films Through MOD Process with Pinning Center Enhancement
Abstract:YBCO film through MOD approach is one of the most cost effective methods for long length CC fabrications. Although, this process has shown success on films below 1 micron, thicker films with performance goal of 500 A/cm have not been demonstrated even on small samples. Increasing Ic through further improving Jc is not viable because the present Jcs are comparable to that of the intragrain Jc, which is believed to be theoretical limit of YBCO superconductors. Thicker films of 1-3 microns through MOD approach with pinning center enhancement are yet to be fully developed to attain a higher Ic. High-density nano scale pinning centers is the only way to keep Jc from dramatic degradation for thick films. Thus, in Phase I, we propose to increase thickness while keeping Jc from degradation for higher Ic. Technical approach including thicker film fabrication and introducing high density nano size pinning centers for the MOD YBCO films on both IBAD and ISD templates are designed. By reaction and growth control, thicker films with high density, uniformly distributed small non-superconducting second phase as pinning centers are expected.

AMBP TECH CORP.
c/o University Buffalo Incubator, 1576 Sweet Home
Amherst, NY 14228
Phone:
PI:
Topic#:
(716) 639-0632
Mr. Nehal Chokshi
OSD 04-EP7      Awarded: 06JAN05
Title:High Energy Density and High Thermally Rated Pulsed Power Capacitor Devices
Abstract:The proposed program by AMBP Tech and Professor Sarjeant's group at SUNY Buffalo will develop and demonstrate a rapid large area deposition process of high energy density amorphous fluorinated carbon (a-C:F) films onto thin aluminum (4um thin) electrode substrates. The innovative research consists of utilizing AMBP Tech's patented high deposition rate technologies of LAMBD or PAMBD tools to optimize the stoichiometry and morphology of a-C:F films in terms of the energy density. Feedback will be provided by evaluating the electrical characteristics of the films via the unique Partial Discharge (PD) analytical setup of the Energy Systems Institute (ESI) directed by Professor Sarjeant.

APSI
3334 Brown Station Road
Columbia, MO 65202
Phone:
PI:
Topic#:
(573) 474-5522
Dr. Michael F. Nichols
OSD 04-EP7      Awarded: 28JAN05
Title:Novel Vacuum Deposited Dielectric Materials for Capacitor Devices
Abstract:Organic film polymers have been the dielectric of choice for high voltage, microsecond-discharge, high energy density capacitors. Electron traps normally found in these films limits their maximun voltage breakdown strength, engergy density, and dissipation. The objective of this proposal is to demonstrate the feasibility of producing higher performance polymer-like dielectric materials without catalysts, impurities, solvents, or antioxidants using ionized cluster beams in conjunction with conventional vacuum deposition techniques.

MATERIALS SCI & TECH APPLICATIONS
409 Maple Springs Dr.
Dayton, OH 45458
Phone:
PI:
Topic#:
(937) 435-6227
Dr. Hao Jiang
OSD 04-EP7      Awarded: 11JAN05
Title:High Performance Dielectric Thin Films Prepared by Homo-/Co-Polymerizations with a Modified Plasma Enhanced Chemical Vapor Deposition (PECVD) Technique
Abstract:The manufacture of high energy density capacitors via the formation of high performance dielectric films is of vital importance for high pulse power applications. MSTA,LLC has demonstrated that by means of a modified PECVD technique, high quality polymer thin films have been fabricated, which are pine-hole free, dense, and homogeneous, with a highly crosslinked 3-dimensional amorphous bulk structure, and a smooth surface. This versatile process also performs plasma co-polymerization from monomers with different functionalities, which can manipulate material refractive index and by extension, the dielectric constant and other dielectric properties of the films. Furthermore, the films are also mechanically tough and robust, possessing excellent thermal stability and chemical/environment resistance, as well as good adhesion on different substrate materials and deposition capability on various shapes of the substrates. MSTA, LLC will do research in the application of this methodology to fabricate dielectric polymer films with high breakdown strength (> 800V/mm), moderate dielectric constants (2.5 - 4), and low dielectric loss (0.1% or less at 1 kHz frequency). Throughout the course of this investigation, the structure/morphology of the films will be examined and elucidated by XPS, IR, solid-state NMR, AFM, SEM, TEM, and spectroscopic ellipsometry to provide a scientifically sound basis for the study of advanced dielectric materials.

NANODYNAMICS, INC.
901 Fuhrmann Blvd.
Buffalo, NY 14203
Phone:
PI:
Topic#:
(832) 978-4386
Mr. Douglas P. DuFaux
OSD 04-EP7      Awarded: 01FEB05
Title:Low-Cost Quasi-Amorphous Carbon Dielectrics for Pulsed Power Capacitors
Abstract:As our military continues to evolve and become more reliant on highly sophisticated equipment, the need for advanced electronics to support their operation is becoming increasingly more important. Clearly, one of the most important transformations is in the area of weapons systems. In fact, the U.S. Military is developing high energy density, pulse power capacitors to enable all-electric weapons with a goal of one day developing only such systems. The capacitors are required building blocks for pulse forming networks (PFNs), which convert prime electrical energy into short pulses needed to energize loads. Some of the current key research objectives for such capacitors include thin, flexible dielectrics with a high voltage breakdown strength (> 20KV/mil), a dielectric constant greater than 2, and low losses (0.1%). Enhanced processing capabilities with potential for radical improvements in materials properties are urgently needed for the development of advanced capacitors. The proposed SBIR program would make ultrahigh performance dielectrics available through an elegant, patent-protected approach to produce synergetic diamond-graphene quasi-amorphous (QUASAMT) materials. These materials have a high dielectric constant, high thermal conductivity, are extremely strong, can be deposited as thin as 5 nanometers, and can be produced at low cost using standard vacuum deposition equipment.

NANOHMICS, INC.
6201 East Oltorf St., Suite 100
Austin, TX 78741
Phone:
PI:
Topic#:
(512) 389-9990
Dr. Keith Jamison
OSD 04-EP7      Awarded: 25JAN05
Title:Novel high strength capacitor dielectrics
Abstract:In this SBIR program Nanohmics propose to fabricate high breakdown strength flexible dielectrics films for use in high voltage capacitors from sputter deposited amorphous oxides. Previous work at Nanohmics has demonstrated a room temperature sputtering technique to deposit exceedingly high quality flexible amorphous nitride films at room temperature with properties similar to their single crystal counterparts. In this program we propose to use a similar growth technique to fabricate amorphous oxides such as ZrO2, HfO2, TiO2 as well as amorphous SiO2. After de